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Infinite terbium(III) chains formed from a tetra-phosphorylated resorcinarene cavitand
Journal article   Peer reviewed

Infinite terbium(III) chains formed from a tetra-phosphorylated resorcinarene cavitand

Hani El Moll, David Semeril, Dominique Matt, Loic Charbonniere and Loic Toupet
Dalton transactions : an international journal of inorganic chemistry, Vol.40(17), pp.4391-4393
01/01/2011
DOI: https://doi.org/10.1039/c0dt01808b
PMID: 21399812

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Reaction of [Tb-III(DMSO)(8)](CF3SO3)(3) with a resorcinarene cavitand substituted by four -CH2P(O)Ph-2 pendant arms afforded an infinite 1D inorganic polymer, in which the consecutive resorcinarene units are linked through two terbium strands, this connection involves pairs of phosphoryl groups occupying adjacent positions of the resorcinarene units.

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