Abstract
Metal complexes of Pb(II), Sn(II), Sb(III) and Bi(III) with a barbital sodium were synthesized and characterized by several techniques, including elemental analysis (C, H and N), molar conductance measurements, infrared, Raman, H-1 NMR. positron annihilation lifetime and thermogravimetric analysis. Reactions of barbital sodium (NaL) with salts of Pb(NO3)(2), SnCl2 center dot 2H(2)O, SbCl3 and BiCl3 affords four novel mononuclear complexes [Pb(HL)(2)]. [Sn(L)(H2O)], [Sb(HL)(L)] and [Bi(HL)(L)]. In complexes of Pb(II), Sb(III) and Bi(III), the molar ratio of metal-to-ligand is 1:2. Both of Sb(III) and Bi(III) complexes have six coordination via two molecules of barbital (HL and L), one of them deprotonated NH. The Pb(II) complex has a central metal ion adopts tetradentate fashion which surrounded by two (HL) barbital moieties. The elemental analysis shows that Sn(II) complex is tetradentate 1:1 ratio, chelated through oxygen -O of (ONa), deprotonated (-NH) and one coordinated water molecule. The positron annihilation lifetime parameters were found to be dependent on the structure, electronic configuration and molecular weight of metal complexes. (C) 2012 Elsevier B.V. All rights reserved.