Infrared intensities as a measure of intramolecular interactions XIX. Electronic interactions in substituted phenyl- and benzyltrimethylsilanes

N.C. Cutress; A.R. Katritzky; F. Eaborn; D.R.M. Walton; R.D. Topsom

doi:10.1016/S0022-328X(00)81773-8

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Infrared intensities as a measure of intramolecular interactions XIX. Electronic interactions in substituted phenyl- and benzyltrimethylsilanes

Journal article

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Infrared intensities as a measure of intramolecular interactions XIX. Electronic interactions in substituted phenyl- and benzyltrimethylsilanes

N.C. Cutress, A.R. Katritzky, F. Eaborn, D.R.M. Walton and R.D. Topsom

Journal of organometallic chemistry, Vol.43(1), pp.127-130

16/09/1972

DOI: https://doi.org/10.1016/S0022-328X(00)81773-8

Abstract

An infrared method has been used to establish that the SiMe 3 group is a weak resonance acceptor in the ground state when joined to a benzene ring. This acceptance is considerably exalted when resonance donors are attached to the para position. The relatively strong resonance donation of a CH 2SiMe 3 group is explicable in terms of hyperconjugation.

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Title: Infrared intensities as a measure of intramolecular interactions XIX. Electronic interactions in substituted phenyl- and benzyltrimethylsilanes
Creators - without role: N.C. Cutress - University of East Anglia
A.R. Katritzky - University of East Anglia
F. Eaborn - University of Sussex
D.R.M. Walton
R.D. Topsom - La Trobe University
Publication Details: Journal of organometallic chemistry, Vol.43(1), pp.127-130
Publisher: Elsevier B.V
Identifiers: 9938580808331
Academic Unit: King Abdulaziz University
Language: English
Resource Type: Journal article