Insertion reactions of organic anhydrides into the Cu–O bond of [CuO t Bu]: syntheses and structures of functionalised copper (I) and copper (II) carboxylates

Lukasz Ponikiewski; Alexander Rothenberger

doi:10.1016/j.ica.2004.10.019

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Insertion reactions of organic anhydrides into the Cu–O bond of [CuO t Bu]: syntheses and structures of functionalised copper (I) and copper (II) carboxylates

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Insertion reactions of organic anhydrides into the Cu–O bond of [CuO t Bu]: syntheses and structures of functionalised copper (I) and copper (II) carboxylates

Lukasz Ponikiewski and Alexander Rothenberger

Inorganica Chimica Acta, Vol.358(4), pp.1322-1326

01/03/2005

DOI: https://doi.org/10.1016/j.ica.2004.10.019

Abstract

Copper (I)alkoxide

Copper carboxylates

Crystal structures

Insertion reactions

Organic anhydride

The insertion reaction of maleic anhydride into the Cu–O bond in [CuO t Bu] produced the complexes [Cu 2(CO 2C 2H 2CO 2 t Bu) 4 · dme] ( 1), [Cu(CO 2C 2H 2CO 2 t Bu) 2 · tmeda] ( 2) and [Cu 2(CO 2C 2H 2CO 2 t Bu) 2 · dppm] 2 ( 3) (dme = 1,2-dimethoxyethane; tmeda = N 1, N 1, N 2, N 2-tetramethylethane-1,2-diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates. The insertion reaction of maleic anhydride into the Cu–O bond in [CuO t Bu] produced the complexes [Cu 2(CO 2C 2H 2CO 2 t Bu) 4 · dme] ( 1), [Cu(CO 2C 2H 2CO 2 t Bu) 2 · tmeda] ( 2) and [Cu 2(CO 2C 2H 2CO 2 t Bu) 2 · dppm] 2 ( 3) (dme = 1,2-dimethoxyethane; tmeda = N 1, N 1, N 2, N 2-tetramethylethane-1,2-diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates.

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Title: Insertion reactions of organic anhydrides into the Cu–O bond of [CuO t Bu]: syntheses and structures of functionalised copper (I) and copper (II) carboxylates
Creators - without role: Lukasz Ponikiewski
Alexander Rothenberger - Karlsruhe Institute of Technology
Publication Details: Inorganica Chimica Acta, Vol.358(4), pp.1322-1326
Publisher: Elsevier B.V
Identifiers: 9942856808331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article