Abstract
The development of high-performance humidity sensors to cater for a plethora of applications, ranging from agriculture to intelligent medical monitoring systems, calls for the selection of a reliable and ultrasensitive sensing material. A simplistic device architecture, robust quantification of ambient relative humidity (% RH), and compatibility with the contemporary integrated circuit technology make a bimodal (capacitive and resistive) surface-type sensor to be a prominent choice for device fabrication. Herein, we have proposed and demonstrated a facile realization of a 5,10,15,20-tetraphenylporphyrinatonickel (II)-zinc oxide (TPPNi-ZnO) nano composite-based bimodal surface-type % RH sensor. The TPPNi macromolecule and ZnO nanoparticles have been synthesized by an eco-benign microwave-assisted technique and a thermal-budget chemical precipitation method, respectively. It is speculated from the morpohological study that specific surface area improvement, via the provision of ZnO nanoparticles on micro-pyramidal structures of TPPNi, may reinforce the sensing properties of the fabricated humidity sensor. The relative humidity sensing capacitive and resistive characteristics of the sensor have been monitored in 40-85% relative humidity (% RH) bandwidth. The fabricated sensor under the biasing conditions of 1 V of applied bias (V-rms) and 500 Hz AC test frequency exhibits a significantly higher sensitivity of 387.03 pF/ % RH and 95.79 k omega/% RH in bimodal operation. The average values of both the response and recovery times of the capacitive sensor have been estimated to be similar to 30 s. It has also been debated why this high degree of sensitivity and considerable reduction in response/recovery time has been obtained. In addition, the intense and wide bandwidth spectral response of the TPPNi-ZnO nanocomposite indicates that it may also be utilized as a potential light-harvesting heterostructured nanohybrid in future studies.