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Interaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with CoX2 (X = Cl, Br) in water: trapping of new self-assembled water chloride/bromide clusters in a [Co(bpca)(2)](+) host (bpca = bis(2-pyrimidylcarbonyl)amidate anion)
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Interaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with CoX2 (X = Cl, Br) in water: trapping of new self-assembled water chloride/bromide clusters in a [Co(bpca)(2)](+) host (bpca = bis(2-pyrimidylcarbonyl)amidate anion)

Damir A. Safin, Patrick M. J. Szell, Antonin Keller, Ilia Korobkov, David L. Bryce and Muralee Murugesu
New journal of chemistry, Vol.39(9), pp.7147-7152
02/07/2015
DOI: https://doi.org/10.1039/c5nj01125f

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
2D polymeric water chloride/bromide sheets comprising a unique pentagon-like dichloride/dibromidetrihydrate cluster in the solid state have been observed as [Co(bpca)(2)](+) (bpca = bis(2-pyrimidylcarbonyl)amidate anion) counterions. Both compounds were obtained by the reaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with CoX2 (X = Cl, Br) in water. Solid-state multinuclear magnetic resonance spectroscopy and XRD provide insight into the structures.

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