Sign in
Back
Interrogating the steric outcome during H-2 heterolysis: in-plane steric effects in the regioselective protonation of the (PNP)-P-3-pincer ligand
Journal article   Open access  Peer reviewed

Interrogating the steric outcome during H-2 heterolysis: in-plane steric effects in the regioselective protonation of the (PNP)-P-3-pincer ligand

Changguang Yao, Tonghuan Zhang, Chunhui Zhou and Kuo-Wei Huang
Dalton transactions : an international journal of inorganic chemistry, Vol.48(34), pp.12817-12821
14/09/2019
DOI: https://doi.org/10.1039/c9dt03003d
PMID: 31403641

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
H-2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2(nd) generation (PNP)-P-3-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H-2 splitting process.
url
https://doi.org/10.1039/c9dt03003dView
Published (Version of record) Open

Metrics

1 Record Views

Details