Upon photolysis
N
-benzyl-2-azidocarbonylpyridinium salts give benzaldehydes, partially
via
the γ-lactams (5).
N
-(2-Phenylethyl) analogues give mixtures of phenylacetaldehydes and benzaldehydes
via
γ-(12) and δ-lactams (13).
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Title
Intramolecular reactions of pyridinium-2-carbonyl azides: conversion of amines into aldehydes
Creators - without role
Alan R Katritzky
Tayyaba Siddiqui
Publication Details
Journal of the Chemical Society, Perkin Transactions 1, (12), pp.2953-2956