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KINETICS AND MECHANISM OF BASE-CATALYZED-HYDROLYSIS OF L-ASPARAGINE AND ITS COPPER(II) COMPLEX
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KINETICS AND MECHANISM OF BASE-CATALYZED-HYDROLYSIS OF L-ASPARAGINE AND ITS COPPER(II) COMPLEX

Z Khan, MZA Rafiquee, M A Niaz and A A Khan
Indian journal of chemistry. Section A, Inorganic, physical, theoretical & analytical, Vol.34(9), pp.737-739
01/09/1995

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Kinetic studies on hydrolysis of L-asparagine and Cu(II)-L-asparagine complex have,been carried out in sodium hydroxide solution (0.1-2.5 mol dm(-3)). The pseudo-first order rate constants follow the general relationship: k(obs) = k(0)[OH-](1)where(\)k(0) is an empirical constant. The probable mechanism of hydrolysis involves monoanionic tetrahedral intermediate. The effect of Cu(II) ion on hydrolysis of L-asparagine has been discussed and activation parameters evaluated.

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