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KINETICS AND MECHANISM OF DECARBOXYLATION OF ALPHA-AMINO-ACIDS BY NINHYDRIN
Journal article   Peer reviewed

KINETICS AND MECHANISM OF DECARBOXYLATION OF ALPHA-AMINO-ACIDS BY NINHYDRIN

Z Khan and A A Khan
Journal of the Indian Chemical Society, Vol.67(12), pp.963-965
01/12/1990

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The kinetic study of decarboxylation of alpha-amino acids has been carried out at various concentrations of ninhydrin at different temperatures (50-80-degrees) and hydrogen ion concentration from 1.0 x 10(-3) to 1.0 x 10(-6) mol dm-3. The reaction follows an irreversible pseudo-first order reaction in presence of excess ninhydrin. The rate of the reaction increases with increase in pH and temperature. On the basis of the observed data a possible mechanism has been proposed.

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