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Kinetics and Thermodynamics of Oxidation of Some meta-substituted Anilines by Tetrabutylammonium Bromochromate in Aqueous Acetic Acid Medium
Journal article   Open access

Kinetics and Thermodynamics of Oxidation of Some meta-substituted Anilines by Tetrabutylammonium Bromochromate in Aqueous Acetic Acid Medium

Shaik Jabir, Basim H. Asghar and S. Sheik Mansoor
Oriental journal of chemistry, Vol.33(1), pp.288-295
01/02/2017
DOI: https://doi.org/10.13005/ojc/330134

Abstract

Biochemistry & Molecular Biology Chemistry Chemistry, Multidisciplinary Life Sciences & Biomedicine Physical Sciences Science & Technology
The tetrabutylammonium bromochromate (TBABC) oxidation of anilines, in an aqueous acetic acid medium in the presence of perchloric acid is described. The reaction is first order with respect to aniline, TBABC and acid. The reaction rate has been determined at different temperatures and activation parameters calculated. The TBABC oxidation of meta-substituted anilines obeys Hammett relationships.
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https://doi.org/10.13005/ojc/330134View
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