Abstract
Lithium recovery from aqueous solutions was studied by trapping lithium ions using a gel of aluminum hydroxide freshly prepared in situ under the reaction of a strong base. A 2(4-1) fractional factorial design and central composite design were employed for experimental design and analysis of the results. The combined effect of molar ratio Al/Li, pH and stirring time on lithium trapping at 25 degrees C was investigated and optimized using response surface methodology (RSM). The optimum values of these factors were found to be 4.7, 7.2 and 3 h respectively. In this case the lithium trapping percent is similar to 95%. The obtained model is highly significant (F-obs>F-tabulate and low p-value) with a correlation coefficient of 96.64%. On the other hand, linear, quadratic and interaction terms in this model have the largest statistical effect on the response (confidence level=99.9%). (C) 2007 Elsevier B.V. All rights reserved.