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Low Catalyst Loadings in Self-Metathesis of 1-Dodecene
Journal article   Peer reviewed

Low Catalyst Loadings in Self-Metathesis of 1-Dodecene

Justyna Czaban, Bryan M. Schertzer and Karol Grela
Advanced synthesis & catalysis, Vol.355(10), pp.1997-2006
08/07/2013

Abstract

Chemistry Chemistry, Applied Chemistry, Organic Physical Sciences Science & Technology
A series of ruthenium catalysts has been screened in the self-metathesis of 1-dodecene with and without the addition of benzoquinones. Many of these catalysts demonstrated excellent selectivity and yields with as low as 10ppm catalyst loading. Reactions have been conducted under decreased pressure or under argon bubbling, which caused a tremendous increase in yield and selectivity of the examined process.

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