A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 degrees C into Zn-methyl. At higher temperatures and with CH4/O-2 or CH4/CO2, it gives methanol and acetic acid respectively.
Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid
Creators - without role
Umesh Patil - King Abdullah University of Science and Technology
Youssef Saih - King Abdullah University of Science and Technology
Edy Abou-Hamad - King Abdullah University of Science and Technology
All Hamieh - King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr KCC, Thuwal 239556900, Saudi Arabia
Jeremie D. A. Pelletier - King Abdullah University of Science and Technology
Jean Marie Basset - King Abdullah University of Science and Technology
Publication Details
Chemical communications (Cambridge, England), Vol.50(82), pp.12348-12351
Publisher
Royal Soc Chemistry
Number of pages
4
Grant note
Saudi Basic Industries Corporation (SABIC)
King Abdullah University of Science and Technology (KAUST); King Abdullah University of Science & Technology