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Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid
Journal article   Peer reviewed

Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

Umesh Patil, Youssef Saih, Edy Abou-Hamad, All Hamieh, Jeremie D. A. Pelletier and Jean Marie Basset
Chemical communications (Cambridge, England), Vol.50(82), pp.12348-12351
21/10/2014
PMID: 25182752

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 degrees C into Zn-methyl. At higher temperatures and with CH4/O-2 or CH4/CO2, it gives methanol and acetic acid respectively.

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