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Magnetically Directed Assembly of Nanocrystals for Catalytic Control of a Three-Component Coupling Reaction
Journal article   Peer reviewed

Magnetically Directed Assembly of Nanocrystals for Catalytic Control of a Three-Component Coupling Reaction

Alaa M. Munshi, Vipul Agarwal, Dominic Ho, Colin L. Raston, Martin Saunders, Nicole M. Smith and K. Swaminathan Iyer
Crystal growth & design, Vol.16(9), pp.4773-4776
07/09/2016

Abstract

Chemistry Chemistry, Multidisciplinary Crystallography Materials Science Materials Science, Multidisciplinary Physical Sciences Science & Technology Technology
Randomly distributed colloidal magnetic nanoparticles in solution are polarized in the presence of an external magnetic field, and the interparticle dipole-dipole attraction drives their assembly into linear chains. In this Communication, we report using a model A(3)-coupling reaction, that the field-directed self assembly of gold-coated magnetite (Fe3O4@Au) nanoparticles can be used to remotely control the rate of reaction by manipulating their colloidal assembly of catalyst in situ.

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