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Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes
Journal article   Peer reviewed

Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes

Johann Bosson, Albert Poater, Luigi Cavallo and Steven P. Nolan
Journal of the American Chemical Society, Vol.132(38), pp.13146-13149
29/09/2010
PMID: 20815384

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Experimental and computational analyses provide support for the existence of a metal-hydride-based mechanism for the ruthenium-mediated racemization of chiral alcohols.

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