Experimental and computational analyses provide support for the existence of a metal-hydride-based mechanism for the ruthenium-mediated racemization of chiral alcohols.
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Title
Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes
Creators - without role
Johann Bosson - Catalan Institute for Water Research
Albert Poater - Catalan Institute for Water Research
Luigi Cavallo - Catalan Institute for Water Research
Steven P. Nolan - Catalan Institute for Water Research
Publication Details
Journal of the American Chemical Society, Vol.132(38), pp.13146-13149
Publisher
Amer Chemical Soc
Number of pages
4
Grant note
Royal Society-Wolfson; Royal Society
ERC; European Research Council (ERC); European Commission
Spanish MICINN; Ministry of Science and Innovation, Spain (MICINN); Spanish Government
HPC facilities CRESCO, Portici, Italy