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Mechanistic insights into the gold chemistry of allenes
Journal article   Peer reviewed

Mechanistic insights into the gold chemistry of allenes

Weibo Yang and A. Stephen K. Hashmi
Chemical Society reviews, Vol.43(9), pp.2941-2955
07/05/2014
PMID: 24671183

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allenes which are based on computational studies, labelling studies, the detection of intermediates, chirality transfer and diastereoselective product formation.

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