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Mechanistic study on benzylic oxidations catalyzed by bismuth(III) salts: X-ray structures of two bismuth-picolinate complexes
Journal article   Peer reviewed

Mechanistic study on benzylic oxidations catalyzed by bismuth(III) salts: X-ray structures of two bismuth-picolinate complexes

Emmanuel Callens, Andrew J. Burton, Andrew J. P. White and Anthony G. M. Barrett
Tetrahedron letters, Vol.49(23), pp.3709-3712
02/06/2008
DOI: https://doi.org/10.1016/j.tetlet.2008.04.044

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
We report studies that are consistent with benzylic oxidation reactions catalyzed using bismuth(III) salts proceeding via a radical mechanism. Additionally, X-ray structures of two potential bismuth-picolinate complex intermediates are reported. (C) 2008 Elsevier Ltd. All rights reserved.

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