Abstract
A mesoporous Zr-G-C3N4 nanomaterial was synthesized by a succinct-step ultrasonication technique and used for Cu2+ ion uptake in the aqueous phase. The adsorption of Cu2+ was examined by varying the operating parameters, including the initial metal concentration, contact time, and pH value. Zr-G-C3N4 nanosorbent displays graphitic carbon nitride (g-C3N4) and ZrO2 peaks with a crystalline size of similar to 14 nm, as determined by XRD analysis. The Zr-G-C3N4 sorbent demonstrated a BET-specific surface area of 95.685 m(2)/g and a pore volume of 2.16 x 10(-7) m(3)center dot g(-1). Batch mode tests revealed that removing Cu (II) ions by the mesoporous Zr-G-C3N4 was pH-dependent, with maximal removal achieved at pH = 5. The adsorptive Cu2+ ion process by the mesoporous nanomaterial surface is well described by the Langmuir isotherm and pseudo-second-order kinetics model. The maximum adsorption capacity of the nanocomposite was determined to be 2.262 mol center dot kg(-1) for a contact time of 48 min. The results confirmed that the fabricated mesoporous Zr-G-C3N4 nanomaterial is effective and regenerable for removing Cu2+ and could be a potent adsorbent of heavy metals from aqueous systems.