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Metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix [4]arenes with cone and 1,3-alternate conformation
Journal article   Peer reviewed

Metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix [4]arenes with cone and 1,3-alternate conformation

Shofiur Rahman, Tomoe Shimizu, Zeng Xi and Takehiko Yamato
Journal of chemical research, Vol.2009(1), pp.1-4
01/01/2009

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Direct O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide afforded two conformational isomers (cone and 1,3-alternate) of tetrakis(carbamoylmethoxy)thiacalix[4]arene and 1,3-disubstituted bis(carbamoylmethoxy)thiacalix [4]arene, depending on the base used.

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