Metathesis of 2-pentene over Mo and W supported mesoporous molecular sieves MCM-41 and SBA-15

Mohamed Ali Ibrahim; Muhammad Naseem Akhtar; Jiri Cejka; Erica Montanari; Hynek Balcar; Martin Kubu; Sulaiman S. Al-Khattaf

doi:10.1016/j.jiec.2017.04.012

Journal article

Metathesis of 2-pentene over Mo and W supported mesoporous molecular sieves MCM-41 and SBA-15

Mohamed Ali Ibrahim, Muhammad Naseem Akhtar, Jiri Cejka, Erica Montanari, Hynek Balcar, Martin Kubu and Sulaiman S. Al-Khattaf

Journal of industrial and engineering chemistry (Seoul, Korea), Vol.53, pp.119-126

25/09/2017

DOI: https://doi.org/10.1016/j.jiec.2017.04.012

Abstract

Chemistry

Chemistry, Multidisciplinary

Engineering

Engineering, Chemical

Physical Sciences

Science & Technology

Technology

Molybdenum and tungsten oxides were supported on silica, MCM-22, MCM-41 and SBA-15. XRD and N-2 adsorption-desorption revealed that architecture and textural character of supports were preserved. The catalysts were investigated in transformation of 2-pentene at different reaction temperatures. MoO3/MCM-22 exhibited highest conversions with isomerization and cracking as major reactions. MoO2(acac)(2), MoO3 and WO3 supported on MCM-41 and SBA-15 showed metathesis reaction of 2-C-5 producing propylene, C-4(-) and C-6+(-) asmajor products. Catalysts based on MCM-41 exhibited higher activity and stability than SBA-15. Addition of ethylene to 2-C-5(-) increased selectivity to propylene due to metathesis of ethylene with 2-pentene. (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

Metrics

1 Record Views

Details

Title: Metathesis of 2-pentene over Mo and W supported mesoporous molecular sieves MCM-41 and SBA-15
Creators - without role: Mohamed Ali Ibrahim - King Fahd University of Petroleum and Minerals
Muhammad Naseem Akhtar - King Fahd University of Petroleum and Minerals
Jiri Cejka - King Fahd University of Petroleum and Minerals
Erica Montanari - Eni
Hynek Balcar - Czech Academy of Sciences, J. Heyrovský Institute of Physical Chemistry
Martin Kubu - Czech Academy of Sciences, J. Heyrovský Institute of Physical Chemistry
Sulaiman S. Al-Khattaf - King Fahd University of Petroleum and Minerals
Publication Details: Journal of industrial and engineering chemistry (Seoul, Korea), Vol.53, pp.119-126
Publisher: Elsevier
Number of pages: 8
Grant note: KFUPM P106/12/0189 / Czech Science Foundation; Grant Agency of the Czech Republic Ministry of Higher Education, Saudi Arabia 14-PET89-04 / King Abdulaziz City for Science and Technology (KACST) through the Science & Technology Unit at King Fahd University of Petroleum & Minerals (KFUPM)
Identifiers: 9947161108331
Academic Unit: King Saud University
Language: English
Resource Type: Journal article