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Methyl 5-bromo-2-[methyl(methylsulfonyl)amino]benzoate
Journal article   Open access

Methyl 5-bromo-2-[methyl(methylsulfonyl)amino]benzoate

Muhammad Shafiq, M. Nawaz Tahir, Islam Ullah Khan, Muhammad Nadeem Arshad and Muneeb Hayat Khan
Acta crystallographica. Section E, Structure reports online, Vol.65(5), pp.O955-U1430
01/05/2009
PMCID: PMC2977655
PMID: 21583998

Abstract

Crystallography Physical Sciences Science & Technology
The title compound, C(10)H(12)BrNO(4)S, is an intermediate in the synthesis of benzothiazine. The planar methyl ester group (maximum deviation is 0.0065 angstrom) is oriented at a dihedral angle of 39.09 (13)degrees with respect to the aromatic ring. In the crystal structure, weak intermolecular C-H center dot center dot center dot O interactions link the molecules into centrosymmetric dimers, through R(2)(2)(10) ring motifs.
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https://doi.org/10.1107/S1600536809011829View
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