Abstract
Reaction of di(benzotriazole-1-yl) methanethione 1 with imines 2a-f gave air and moisture stable benzotriazolyl beta-enaminothiones 3a-f. The thioacylbenzotriazoles 3a-f enable simple and efficient preparation of beta-enamino thioic acid derivatives (thioamides, thioesters and dithioesters) in 74-99% yields via microwave mediated nucleophilic substitution of the benzotriazolyl moiety. C-Thioacylation with 1-thioacyl-6-nitrobenzotriazoles 7a-c is also discussed.