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Migratory insertion of [B(C6F5)(2)] into C-H bonds: CO promoted transfer of the boryl fragment
Journal article   Peer reviewed

Migratory insertion of [B(C6F5)(2)] into C-H bonds: CO promoted transfer of the boryl fragment

Simon Aldridge, Deborah L. Kays (nee Coombs), Amal Al-Fawaz, Kevin M. Jones, Peter N. Horton, Michael B. Hursthouse, Ross W. Harrington and William Clegg
Chemical communications (Cambridge, England), (24), pp.2578-2580
01/01/2006
DOI: https://doi.org/10.1039/b604141h
PMID: 16779483

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The reaction of (eta(5)-C5H5)Fe(CO)(2)B(C6F5)(2) with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment ( via C - H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)(2)H]Fe(CO)(3) in quantitative yield.

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