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Mixed-metal coordination networks constructed from Hg(CN)(2) rods and Hg center dot center dot center dot N-az (az = azide) secondary interactions: Syntheses and structures of Hg(CN)(2)center dot(N-3)(2)center dot Cu(C5H5N)(2) and NaHg(CN)(2)center dot(N-3)(2)center dot Cu(N-3)(C3H10N2)(2)
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Mixed-metal coordination networks constructed from Hg(CN)(2) rods and Hg center dot center dot center dot N-az (az = azide) secondary interactions: Syntheses and structures of Hg(CN)(2)center dot(N-3)(2)center dot Cu(C5H5N)(2) and NaHg(CN)(2)center dot(N-3)(2)center dot Cu(N-3)(C3H10N2)(2)

William T. A. Harrison, Ejaz, Islam Ullah Khan and imran Khan
Polyhedron, Vol.30(13), pp.2181-2185
23/08/2011
DOI: https://doi.org/10.1016/j.poly.2011.05.049

Abstract

Chemistry Chemistry, Inorganic & Nuclear Crystallography Physical Sciences Science & Technology
The syntheses and crystal structures of Hg(CN)(2)center dot(N-3)(2)center dot Cu(C5H5N)(2) (1) and NaHg(CN)(2)center dot(N-3)(2)center dot Cu(N-3)(C3H10N2)(2) (2) are reported. The interplay between linear Hg(CN)(2) and N-3(-) building units by way of long Hg center dot center dot center dot N secondary interactions leads to new types of hybrid inorganic-organic networks in these phases. (C) 2011 Elsevier Ltd. All rights reserved.

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