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Mo(CO)(6) catalysed chemoselective hydrosilylation of alpha,beta-unsaturated amides for the formation of allylamines
Journal article   Peer reviewed

Mo(CO)(6) catalysed chemoselective hydrosilylation of alpha,beta-unsaturated amides for the formation of allylamines

Alexey Volkov, Fredrik Tinnis, Tove Slagbrand, Ida Pershagen and Hans Adolfsson
Chemical communications (Cambridge, England), Vol.50(93), pp.14508-14511
01/01/2014
DOI: https://doi.org/10.1039/c4cc07150f
PMID: 25307061

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Molybdenum hexacarbonyl (Mo(CO)(6)) was used as an efficient catalyst for the chemoselective reduction of the amide functionality in alpha,beta-unsaturated compounds, under hydrosilylation conditions using 1,1,3,3-tetramethyldisiloxane (TMDS) as the hydride source.

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