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Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
Journal article   Open access  Peer reviewed

Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

Justyna Czaban-Jozwiak, Lukasz Wozniak, Artur Ulikowski, Katarzyna Kwiecinska, Adam A. Rajkiewicz and Karol Grela
Molecules (Basel, Switzerland), Vol.23(7), p.1722
14/07/2018
DOI: https://doi.org/10.3390/molecules23071722
PMCID: PMC6099925
PMID: 30011916

Abstract

Biochemistry & Molecular Biology Chemistry Chemistry, Multidisciplinary Life Sciences & Biomedicine Physical Sciences Science & Technology
The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.
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https://doi.org/10.3390/molecules23071722View
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