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Modulating the packing of [Cu-24(isophthalate)(24)] cuboctahedra in a triazole-containing metal-organic polyhedral framework
Journal article   Open access  Peer reviewed

Modulating the packing of [Cu-24(isophthalate)(24)] cuboctahedra in a triazole-containing metal-organic polyhedral framework

Yong Yan, Mikhail Suyetin, Elena Bichoutskaia, Alexander J. Blake, David R. Allan, Sarah A. Barnett and Martin Schroeder
Chemical science (Cambridge), Vol.4(4), pp.1731-1736
01/01/2013
DOI: https://doi.org/10.1039/c3sc21769h

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The highly porous (3,24)-connected framework NOTT-122 incorporates a C-3-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu-24(isophthalate)(24)] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H-2, CH4 and CO2 adsorption capacities in desolvated NOTT-122a.
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https://doi.org/10.1039/c3sc21769hView
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