Abstract
Structural features of localization of chiral isomers of 1-phenylethanol (R-PhEtOH and S-PhEtOH) and their mobility activation in homochiral metal-organic [Zn-2(bdc)(S-lac)(dmf)] sorbent were studied with H-1 and C-13 NMR methods. 13C NMR chemical shifts do not show obvious advantage of selective interaction of molecule guests. But activation molecular mobility of S-PhEtOH and R-PhEtOH clearly indicates that stabilization of [Zn-2(bdc)(S-lac)(dmf)]center dot S-PhEtOH structure is more preferable than stabilization of [Zn-2(bdc)(S-lac)(dmf)]center dot R-PhEtOH structure. Copyright (C) 2015 John Wiley & Sons, Ltd.