Abstract
THE EFFICIENCY of excited-state interaction between Tb3+ and the 4'carboxybenzo-18crown-6-ether (CCE) has been studied in different solvents and pH. The high luminescence intensity of Tb-complex in DMF at 545 nm was obtained. The photo physical properties of the green emissive Tb3+ complex have been elucidated. The Tb- CCE was used as photo probe for the assessment of Nalbuphine HCl in the pharmaceutical amp and serum samples at pH 6.5 and lambda(ex) = 285 nm with a linear range 5x10(-8) to 1.2x10(-6) mol L-1 of Nalbuphine HCl, correlation coefficient of 0.993 and detection limit of 9.4 x10(-9) mol L-1.