Abstract
Well-dispersed ZnO(x)CeO2(1-x) nanodots@carbon nanofibers as anode catalysts for the electrooxidation of methanol were synthesized by an easy-controlled template-free method. Their structure and morphology were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), field-emission scanning electron microscopy (FESEM) equipped with rapid EDX (energy dispersive analysis of X-ray). The appealed characterization techniques specified that the obtained material is carbon nanofibers decorated by ZnO and CeO2 nanodots. The electrochemical oxidation of methanol on ZnO(x)CeO2(1-x) nanodots@CNFs modified glassy carbon electrode in alkaline solutions was systematically evaluated by cyclic voltammetry (CV) method. A detailed investigation is made for the electrocatalytic oxidation of methanol by varying methanol concentration. The corresponding current densities of ZnO(60%)CeO2(40%) nanodots@CNFs and ZnO(40%)CeO2(60%) nanodots@CNFs were 5.3 and 16.3 mA/cm(2), respectively. Moreover, negative onset potential (-50 mV vs. Ag/AgCl) was observed when ZnO(40%)CeO2(60%) nanodots@CNFs were utilized, which is a superior value among the reported non-precious electrocatalysts. These results suggested cheap and effective nanomaterials as non-precious catalyst for DMFCs application and pave the way to further improve the performance in energy and environmental applications. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.