Abstract
Electrocatalytic nitrite (NO2-) reduction to ammonia (NH3) can not only synthesize value-added NH3, but also remove NO2- pollutants from the environment. However, the low efficiency of NO2--to-NH3 conversion hinders its applications. Here, Ni nanoparticle-decorated juncus-derived biomass carbon prepared at 800 degrees C (Ni@JBC-800) serves as an efficient catalyst for NH3 synthesis by selective electroreduction of NO2-. This catalyst shows a remarkable NH3 yield of 4117.3 mu g h(-1) mg(cat.)(-1) and a large faradaic efficiency of 83.4% in an alkaline electrolyte. The catalytic mechanism is further investigated by theoretical calculations.