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Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway
Journal article   Peer reviewed

Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway

Shao-Chi Lee, Lin Guo, Huifeng Yue, Hsuan-Hung Liao and Magnus Rueping
Synlett, Vol.28(19), pp.2594-2598
01/12/2017
DOI: https://doi.org/10.1055/s-0036-1591495

Abstract

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Abstract A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon–heteroatom bond formations in a straightforward and mild fashion.

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