Abstract
In this paper, the thermal behavior of large pieces of wood pyrolysis has been modeled. Two mathematical models coupling heat transfer equations to chemical kinetics were used to predict the pyrolytic degradation of a 25 mm radius wood sample, assumed to be dry in the first model and wet in the second, when heated to 973.15 K. The reactions involved in the pyrolysis process are assumed to be endothermic. The diffusion of bounded water during the process is taken into account in the second model, where the heat transfer equation has been coupled to that of the diffusion of moisture. This model, although simple, provides more information on the drying and pyrolysis processes during the heating of wood, which is its originality. It can therefore be advantageously used to calculate the temperature distribution in a pyrolysis bed. The equations of the two models, discretized by an explicit finite difference method, were solved numerically by a program written in Python. The validation of both models against experimental work in the literature is satisfactory. The two models allow examination of the temperature profile in the radial direction of wood samples and highlighting of the effect of temperature on some thermal, physical and physicochemical characteristics.