One-Pot Approach to the Conversion of Alcohols into α-Iodo-α,β-unsaturated Esters

Usama Karama

doi:10.1080/00397910903434570

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One-Pot Approach to the Conversion of Alcohols into α-Iodo-α,β-unsaturated Esters

Journal article

Peer reviewed

One-Pot Approach to the Conversion of Alcohols into α-Iodo-α,β-unsaturated Esters

Usama Karama

Synthetic communications, Vol.40(23), pp.3447-3451

03/11/2010

DOI: https://doi.org/10.1080/00397910903434570

Abstract

Iodo

iodoylides

one-pot synthesis

oxidation

unsaturated esters

(Carboethoxymethylene)triphenylphosphorane 1 can undergo the tandem reaction of iodination-oxidation-Wittig reaction with alcohol in the presence of N-iodosuccinimide (NIS) and manganese dioxide. The reaction constitutes a stereoselective one-pot procedure for the preparation of Z-configured α -iodo- α , β -unsaturated esters in good to excellent yield.

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Title: One-Pot Approach to the Conversion of Alcohols into α-Iodo-α,β-unsaturated Esters
Creators - without role: Usama Karama - King Saud University
Publication Details: Synthetic communications, Vol.40(23), pp.3447-3451
Publisher: Taylor & Francis Group
Identifiers: 9950107008331
Academic Unit: King Saud University
Language: English
Resource Type: Journal article