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Organocatalytic asymmetric 5-hydroxyisoxazolidine synthesis: A highly enantioselective route to beta-amino acids
Journal article   Peer reviewed

Organocatalytic asymmetric 5-hydroxyisoxazolidine synthesis: A highly enantioselective route to beta-amino acids

Ismail Ibrahem, Ramon Rios, Jan Vesely, Gui-Ling Zhao and Armando Cordova
Chemical communications (Cambridge, England), (8), pp.849-851
01/01/2007
PMID: 17308652

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The highly chemo- and enantioselective organocatalytic tandem reaction between N-protected hydroxyl amines and a, beta-unsaturated aldehydes is presented; the reaction provides access to 5-hydroxyisoxazolidines and beta-amino acids in high yields and with 90-99% ee.

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