Sign in
Back
Oxidative Intramolecular 1,2-Amino-Oxygenation of Alkynes under Au-I/Au-III Catalysis: Discovery of a Pyridinium-Oxazole Dyad as an Ionic Fluorophore
Journal article   Peer reviewed

Oxidative Intramolecular 1,2-Amino-Oxygenation of Alkynes under Au-I/Au-III Catalysis: Discovery of a Pyridinium-Oxazole Dyad as an Ionic Fluorophore

Aslam C. Shaikh, Dnyanesh S. Ranade, Pattuparambil R. Rajamohanan, Prasad P. Kulkarni and Nitin T. Patil
Angewandte Chemie (International ed.), Vol.56(3), pp.757-761
16/01/2017
DOI: https://doi.org/10.1002/anie.201609335
PMID: 28000332

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Oxidative intramolecular 1,2-amino-oxygenation reactions, combining gold(I)/gold(III) catalysis, is reported. The reaction provides efficient access to a structurally unique ionic pyridinium-oxazole dyad with tunable emission wavelengths. The application of these fluorophores as potential biomarkers has been investigated.

Metrics

1 Record Views

Details