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Palladacycle containing nitrogen and selenium: highly active pre-catalyst for the Suzuki-Miyaura coupling reaction and unprecedented conversion into nano-sized Pd17Se15
Journal article   Peer reviewed

Palladacycle containing nitrogen and selenium: highly active pre-catalyst for the Suzuki-Miyaura coupling reaction and unprecedented conversion into nano-sized Pd17Se15

Gyandshwar Kumar Rao, Arun Kumar, Jahangeer Ahmed and Ajai Kumar Singh
Chemical communications (Cambridge, England), Vol.46(32), pp.5954-5956
01/01/2010
DOI: https://doi.org/10.1039/c0cc01075h
PMID: 20625588

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Newly synthesized, air and moisture insensitive palladacycle [PdCl(L-H)] (L = (C6H5)(2-HOC6H4) CHNH(CH2)(3)SePh; a (N, Se, C-) ligand) shows high catalytic activity for the Suzuki-Miyaura coupling reaction of phenylboronic acid with aryl/heteroaryl chlorides/bromides (TON for aryl chlorides up to 9200) and is converted to similar to 8 nm size particles of Pd17Se15 (probably the real catalyst).

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