Abstract
A novel binuclear phenoxo-bridged zinc complex obtained from the interaction of ligand, 2,2-(1E,1E)-(2,2-dimethylpropane-1,3-diyl)bis(azanylylidene) bis(methanylylidene)diphenol with zinc chloride is reported. The synthesized and isolated zinc complex has been characterized by FT-IR, H-1- and C-13- NMR, ESI-MS, TGA/DTA and single crystal X-ray diffraction studies. The phenoxo-bridge in this binuclear Zn(II) complex is due to the phenolic oxygen of the salen liagnd. The complex crystallizes in monoclinic P-1 space group, and different geometry has been assigned for both zinc ions in the complex. (C) 2015 Elsevier B.V. All rights reserved.