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Phosphide coupling in the reaction of Sn(NMe2)(2) with MesPHLi; synthesis and structure of the Sn(II) phosphide dianion [{Sn(mu-PMes)}(2)(MesP)(2)](2-) (Mes=2,4,6-Me3C6H2)
Journal article   Peer reviewed

Phosphide coupling in the reaction of Sn(NMe2)(2) with MesPHLi; synthesis and structure of the Sn(II) phosphide dianion [{Sn(mu-PMes)}(2)(MesP)(2)](2-) (Mes=2,4,6-Me3C6H2)

A D Bond, A Rothenberger, A D Woods and D S Wright
Chemical communications (Cambridge, England), (6), pp.525-526
01/01/2001
DOI: https://doi.org/10.1039/b010201f

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
In contrast to the reactions of other primary phosphides with Sn(NMe2)(2), the reaction of MesPHLi with Sn(NMe2)(2) results in partial coupling of MesP groups in the product (which contains the novel Sn(ii) dianion [{(Sn(mu -PMes)}(2)-(MesP)(2)](2-)).

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