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Polymeric arrangements of P-Se anions and a first insight into their reactivity
Journal article   Peer reviewed

Polymeric arrangements of P-Se anions and a first insight into their reactivity

Weifeng Shi, Maryam Shafaei-Fallah, Christopher E. Anson and Alexander Rothenberger
Dalton transactions : an international journal of inorganic chemistry, (24), pp.2979-2983
01/01/2006
DOI: https://doi.org/10.1039/b601704e
PMID: 16770457

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)mu-Se](2) with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P - Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe3](2-) or [PhPSe2Se - SeSe2PPh](2-) dianions are observed and the mechanisms of their formation described.

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