Abstract
We have investigated the polymorphic phase transformations above ambient temperature for 3-chloro-trans-cinnamic acid (3-ClCA, C9H7ClO2) and a solid solution of 3-ClCA and 3-bromo-trans-cinnamic acid (3-BrCA, C9H7BrO2). At 413 K, the gamma polymorph of 3-ClCA transforms to the beta polymorph. Interestingly, the structure of the beta polymorph of 3-ClCA obtained in this transformation is different from the structure of the beta polymorph of 3-BrCA obtained in the corresponding polymorphic transformation from the gamma polymorph of 3-BrCA, even though the gamma polymorphs of 3-ClCA and 3-BrCA are isostructural. We also report a high-temperature phase transformation from a gamma-type structure to a beta-type structure for a solid solution of 3-ClCAand 3-BrCA(with a molar ratio close to 1:1). The gamma polymorph of the solid solution is isostructural with the gamma polymorphs of pure 3-ClCA and pure 3-BrCA, while the gamma-type structure produced in the phase transformation is structurally similar to the beta polymorph of pure 3-BrCA.