Sign in
Back
Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination
Journal article   Peer reviewed

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica C. So, M. Hassan Beyzavi, Rohan Sawhney, Osama Shekhah, Mohamed Eddaoudi, Salih S. Al-Juaid, Joseph T. Hupp and Omar K. Farha
Chemical communications (Cambridge, England), Vol.51(1), pp.85-88
04/01/2015
DOI: https://doi.org/10.1039/c4cc05727a
PMID: 25325833

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

Metrics

1 Record Views

Details