The first air-stable, crystalline carbamylsilane, (Me
3SiC(O)NMe
2 has been prepared and characterized by an X-ray crystallographic study. Photolysis of the carbamylsilane does not give rise to an
N-substituted silene.
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Title
Preparation and X-ray crystal structure of a carbamylsilane
Creators - without role
Salih S. Al-Juaid
Youcef Derouiche
Peter B. Hitchcock
Paul D. Lichiss
Adrian G. Brook - University of Toronto
Publication Details
Journal of organometallic chemistry, Vol.403(3), pp.293-298