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Preparations of Trisubstituted Hydrazines and Pyrazolidines from N-(1-Benzotriazolylalkyl)hydrazines
Journal article   Peer reviewed

Preparations of Trisubstituted Hydrazines and Pyrazolidines from N-(1-Benzotriazolylalkyl)hydrazines

Alan R. Katritzky, Guofang Qiu and Baozhen Yang
Journal of organic chemistry, Vol.62(23), pp.8210-8214
14/11/1997
PMID: 11671935

Abstract

Reactions of N,N'-disubstituted hydrazines with benzotriazole and aldehydes give N-(alpha-benzotriazoylalkyl)-N,N'-disubstituted hydrazines which on treatment with organometallic reagents form N-alkyl-N,N'-disubstituted hydrazines in good yields. N-(Benzotriazolylalkyl)-N,N'-disubstituted hydrazines and electron-rich olefins, in the presence of zinc bromide catalyst, generate N,N'-disubstituted pyrazolidines in moderate to good yields.

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