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Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors
Journal article   Peer reviewed

Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors

Xueliang Shi, Sangsu Lee, Minjung Son, Bin Zheng, Jingjing Chang, Linzhi Jing, Kuo-Wei Huang, Dongho Kim and Chunyan Chi
Chemical communications (Cambridge, England), Vol.51(67), pp.13178-13180
01/01/2015
DOI: https://doi.org/10.1039/c5cc04243g
PMID: 26199107

Abstract

A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS.

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