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Programmed assembly of 4,2 ':6 ',4 ''-terpyridine derivatives into porous, on-surface networks
Journal article   Open access  Peer reviewed

Programmed assembly of 4,2 ':6 ',4 ''-terpyridine derivatives into porous, on-surface networks

Thomas Nijs, Frederik J. Malzner, Shadi Fatayer, Aneliia Waeckerlin, Sylwia Nowakowska, Edwin C. Constable, Catherine E. Housecroft and Thomas A. Jung
Chemical communications (Cambridge, England), Vol.51(61), pp.12297-12300
01/01/2015
DOI: https://doi.org/10.1039/c5cc04186d
PMID: 26138906

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The use of divergent, V-shaped, 4,2': 6',4 ''-terpyridine building blocks that self-assemble into hydrogen-bonded domains and upon addition of copper atoms undergo metallation with concomitant transformation into a coordination network is described; multiple energetically similar structural motifs are observed in both hydrogen-bonded and adatom-coordinated networks.
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https://doi.org/10.1039/c5cc04186dView
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