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Push-pull triazenes derived from 1-(benzylideneamino)- and 1-(sulfonimido)-azolylidenes
Journal article   Peer reviewed

Push-pull triazenes derived from 1-(benzylideneamino)- and 1-(sulfonimido)-azolylidenes

Davit Jishkariani, C Dennis Hall, Aydin Demircan, Blake J Tomlin, Peter J Steel and Alan R Katritzky
Journal of organic chemistry, Vol.78(7), pp.3349-3354
05/04/2013
DOI: https://doi.org/10.1021/jo302697q
PMID: 23390958

Abstract

Azoles - chemistry Benzylidene Compounds - chemistry Molecular Structure Stereoisomerism Sulfonamides - chemistry Triazenes - chemical synthesis Triazenes - chemistry
In-situ-generated neutral 1-(benzylideneamino)- and novel anionic 1-(sulfonimido)-azolylidenes react with organic azides to afford diverse classes of push-pull triazenes and triazene salts. The scope of the heterocyclic core and substituents at the N1 and N3 positions of NHC precursors together with the thermal properties of resulting compounds were examined.

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