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Radical ion pair mediated triplet formation in polymer-fullerene blend films
Journal article   Peer reviewed

Radical ion pair mediated triplet formation in polymer-fullerene blend films

Hideo Ohkita, Steffan Cook, Yeni Astuti, Warren Duffy, Martin Heeney, Steve Tierney, Iain McCulloch, Donal D C Bradley and James R Durrant
Chemical communications (Cambridge, England), (37), pp.3939-3941
01/01/2006
PMID: 17268677

Abstract

Biomimetic Materials - chemistry Free Radicals - chemistry Fullerenes - chemistry Ions Kinetics Molecular Structure Polymers - chemistry Spectrophotometry, Ultraviolet Thiophenes - chemistry
Efficient triplet formation is observed for films of high ionisation potential polythiophenes blended with a fullerene derivative, and assigned to formation via geminate charge recombination of bound radical ion pair states.

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