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Reactions of copper acetylides. Structure of (π-C5H5)Ru(PPh3)2 (CCPh)CuCl, and new syntheses of transition metal cluster compounds
Journal article   Peer reviewed

Reactions of copper acetylides. Structure of (π-C5H5)Ru(PPh3)2 (CCPh)CuCl, and new syntheses of transition metal cluster compounds

M.I. Bruce, O.M.Abu Salah, R.E. Davis, N.V. Raghavan and Omar M. Abu-Salah
Journal of organometallic chemistry, Vol.64(3), pp.C48-C50
15/01/1974
DOI: https://doi.org/10.1016/S0022-328X(00)92171-5

Abstract

In contrast to a related iron—copper compound, the complex (π-C5H5)Ru(PPh3)2(C2Ph)CuCl is shown to be monomeric, and contains linear dicoordinate copper(I); the reactions of this and similar complexes with metal carbonyls are sources of new mixed-metal clusters, such as (π-C5H5)Fe2 Ru(C2Ph)(CO)6 (PPh3).

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